Site-directed regiocontrolled synthesis of a 'head-to-head' photodimer via a single-crystal-to-single-crystal transformation involving a linear template.
نویسندگان
چکیده
Co-crystallisation of 1,8-naphthalenedicarboxylic acid (1,8-nap) with trans-1-(3-pyridyl)-2-(4-pyridyl)ethylene (3,4-bpe) gives a discrete molecular solid-state assembly, 2(3,4-bpe).2(1,8-nap) 1, that is held together by four O-H...N hydrogen bonds wherein the diacid directs a regiocontrolled [2 + 2] photodimerization; the reaction occurs by way of a single-crystal-to-single-crystal transformation.
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ورودعنوان ژورنال:
- Chemical communications
دوره 17 شماره
صفحات -
تاریخ انتشار 2002